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Arsenic ( As )

Material Information

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General Description:  

Discovered in the 13th. century by Albertus Magnus (although believed to have been used much earlier as an alloying addition to bronze to provide a lustrous finish).

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Arsenic is found in several allotropic forms and has both metallic and non-metallic properties. The grey metallic allotrope is a brittle, crystalline solid which tarnishes readily in air and burns in oxygen. It is resistant to attack by dilute acids and alkalis, but will react with hot acids and molten NaOH. Arsenic is poisonous (it is thought to have been responsible for the death of Napoleon) and occurs both free and combined in many minerals (Arsenic has an abundance within the earth's crust of 1.5 ppm). Applications for grey arsenic include its use as an alloying element, its use in the manufacture of certain types of glass and as a donor impurity in germanium semiconductor devices. The non-metallic allotropes include yellow arsenic (may be formed by rapid condensation of Arsenic vapour in an inert atmosphere) and black arsenic (may be formed by slow condensation of the vapour in an inert atmosphere).

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Atomic Properties

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Atomic number 33 Atomic radius - Goldschmidt ( nm ) 0.125 Atomic weight ( amu ) 74.9216 Crystal structure Rhombohedral Electronic structure Ar 3d1O 4s2 4p3 Ionisation potential No. eV 1 9.81 2 18.6 3 28.4 4 50.1 5 62.6 6 128 Natural isotope distribution Mass No. % 75 100 Photo-electric work function ( eV ) 5.1 Thermal neutron absorption cross-section ( Barns ) 4.3 Valences shown -3, 0, 3, 5

Electrical Properties

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Electrical resistivity @20C ( µOhmcm ) 33.3

Mechanical Properties

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Material condition Polycrystalline Bulk modulus ( GPa ) 22.0 Hardness - Vickers 57-69

Physical Properties

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Boiling point ( C ) 616 Density @20C ( g cm-3 ) 5.73 Melting point ( C ) Sublimes >300

Thermal Properties

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Coefficient of thermal expansion @0-100C ( x10-6 K-1 ) 5.6 Latent heat of fusion ( J g-1 ) 370 Specific heat @25C ( J K-1 kg-1 ) 328 Thermal conductivity @0-100C ( W m-1 K-1 ) 50.2

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